Ch.22 | Test Bank Docx – Organic Compounds, Polymers, And - Solution Bank | Chemistry Molecular Nature 8e by Neil D. Jespersen. DOCX document preview.

Ch.22 | Test Bank Docx – Organic Compounds, Polymers, And

Chemistry: Molecular Nature of Matter, 8e (Jespersen)

Chapter 22 Organic Compounds, Polymers, and Biochemicals

1) How many isomers are there of butane, C4H10?

A) 1 (no isomers)

B) 2

C) 3

D) 4

E) 5

Diff: 1

Section: 22.1

2) How many isomers are there of propane, C3H8?

A) 1 (no isomers)

B) 2

C) 3

D) 4

E) 5

Diff: 1

Section: 22.1

3) How many isomers are there of pentane, C5H12?

A) 1 (no isomers)

B) 2

C) 3

D) 4

E) 5

Diff: 1

Section: 22.1

4) CH3—CH2—O—H and CH3—O—CH3 are a pair of compounds that are

A) allotropes.

B) allomers.

C) isochrones.

D) isomers.

E) allotones.

Diff: 1

Section: 22.1

5) CH3—CH2—NH2 and CH3—NH—CH3 are a pair of compounds that are

A) allotropes.

B) allomers.

C) isochrones.

D) isomers.

E) allotones.

Diff: 1

Section: 22.1

6) The functional group, —O—H, is found in which one of these types of organic compounds?

A) alkanes

B) alkenes

C) amines

D) alcohols

E) ethers

Diff: 1

Section: 22.1

7) The functional group, —NH2, is found in which one of these types of organic compounds?

A) alkanes

B) alkenes

C) amines

D) alcohols

E) ethers

Diff: 1

Section: 22.1

8) The functional group, R—O—R, is found in which one of these types of organic compounds?

A) alkanes

B) alkenes

C) amines

D) alcohols

E) ethers

Diff: 1

Section: 22.1

9) Draw a structural formula for cyclohexane, a cyclic saturated hydrocarbon (C6H12). How many σ-bonds are in cyclohexane?

A) 12

B) 16

C) 17

D) 18

E) 20

Diff: 1

Section: 22.1

10) Draw a structural formula for cyclohexane, a cyclic saturated hydrocarbon (C6H12). How many π-bonds are in a cyclohexane molecule?

A) 0

B) 2

C) 3

D) 4

E) 6

Diff: 1

Section: 22.1

11) How many isomers are there of propene, H2C═CH—CH3?

A) 1 (no isomers)

B) 2

C) 3

D) 4

E) 5

Diff: 2

Section: 22.1

12) A saturated 8-carbon straight chain hydrocarbon would have how many hydrogens?

A) 8

B) 10

C) 16

D) 18

E) 24

Diff: 1

Section: 22.1

13) Butene, C4H8, is a hydrocarbon with one double bond. How many isomers are there of butane?

A) 1 (no isomers)

B) 2

C) 3

D) 4

E) 5

Diff: 1

Section: 22.2

14) Which compound is butane?

A) CH3CH3

B) CH3CH2CH3

C) CH3CH2CH2CH3

D) CH3CH2CH2CH2CH3

E) CH3CH2CH2CH2CH2CH3

Diff: 1

Section: 22.2

15) Which compound is pentane?

A) CH3CH3

B) CH3CH2CH3

C) CH3CH2CH2CH3

D) CH3CH2CH2CH2CH3

E) CH3CH2CH2CH2CH2CH3

Diff: 1

Section: 22.2

16) Which compound is a butene?

A) CH≡CH

B) CH2═CH—CH3

C) CH3—CH2—CH2—CH3

D) CH3—CH2—CH3

E) CH3—CH2—CH═CH2

Diff: 1

Section: 22.2

17) Which compound is pentane?

A) CH3—CH2—CH2—CH3

B) CH2═CH—CH═CH2

C) CH3—CH═CH—CH2—CH3

D) CH3—CH2—CH2—CH2—CH3

E) CH3—CH2—CH2—CH2—CH2—CH3

Diff: 1

Section: 22.2

18) Which one of the groups below goes by the name propyl?

A) CH3—CH2—

B) CH2—CH—

C) CH3—CH2—CH2—

D) CH2—CH—CH2—

E) CH3—CH—CH—

Diff: 1

Section: 22.2

19) The alkyl group, —CH3, where the open bond shows where it attaches to a larger carbon chain, is named

A) methide

B) methonium

C) methal

D) methyl

E) trihydrogencarbide

Diff: 1

Section: 22.2

20) The alkyl group shown below, where the open bond shows where it attaches to a larger carbon chain, is named

The structure of an alkyl group has a three-carbon chain, in which C 2 has an open bond.

A) propyl

B) propide

C) propanium

D) isopropyl

E) propanyl

Diff: 1

Section: 22.2

21) Which compound is not an unsaturated compound?

A) H2C═CH2

B) CH3—CH═CH2

C) H2C═CH—Cl

D) CH3—CH2—O—H

E) H2C═CH—O—H

Diff: 1

Section: 22.2

22) Which compound is not an unsaturated compound?

A) H2C═CH—CH2—O—H

B) CH3—CH═CH2

C) H2C═CH—O—H

D) H2C═CH—Cl

E) CH3—CH2—NH2

Diff: 1

Section: 22.2

23) Which of the following is true about the benzene molecule?

A) It is a straight chain hydrocarbon.

B) It contains a heterocyclic oxygen.

C) It is a saturated hydrocarbon.

D) The double bonds in its ring have resonance and their electrons are delocalized.

E) Attachments to the ring can exhibit cis/trans isomerism.

Diff: 1

Section: 22.2

24) In the IUPAC system of nomenclature, the alkane hydrocarbon whose skeleton is shown below, is regarded as a derivative of

The skeleton structure of an alkane molecule has a seven-carbon chain, in which C 2 is bonded to a methyl group.

A) butane.

B) hexane.

C) heptane.

D) octane.

E) pentane.

Diff: 1

Section: 22.2

25) In the IUPAC system of nomenclature, the alkane hydrocarbon whose skeleton is shown below, is regarded as a derivative of

The skeleton structure of an alkane molecule has an eight-carbon chain. C 4 is bonded to a methyl group and C 2 of a three-carbon chain.

A) dodecane.

B) decane.

C) heptane.

D) pentane.

E) octane.

Diff: 2

Section: 22.2

26) The IUPAC name (don't worry about geometric isomers) for the compound,

CH3—CH═CH—CH3, is

A) butene-2.

B) butene-3.

C) 2-butene.

D) 2-butyne.

E) 3-butene.

Diff: 1

Section: 22.2

27) The IUPAC name for the compound, H2C═CH—CH═CH2, is

A) butene-2.

B) 1.3-dibutene.

C) 1,3-butadiene.

D) butane-1,3.

E) 2-butynel.

Diff: 1

Section: 22.2

28) If two of the hydrogen atoms in butane are replaced by two chlorine atoms, how many different dichlorobutane isomers can there be?

A) 1

B) 2

C) 3

D) 4

E) 6

Diff: 1

Section: 22.2

29) If two of the hydrogen atoms on a single carbon in pentane are replaced by two chlorine atoms, how many different dichloropentane isomers can there be?

A) 2

B) 3

C) 4

D) 5

E) 6

Diff: 1

Section: 22.2

30) Draw a structural formula for benzene. How many σbonds are in the molecule?

A) 6

B) 12

C) 14

D) 18

E) 20

Diff: 1

Section: 22.2

31) Draw a structural formula for benzene. How many single and double bonds are in the benzene molecule?

A) 3 single, 0 double

B) 6 single, 2 double

C) 3 single, 2 double

D) 9 single, 23 double

E) 12 single, 3 double

Diff: 1

Section: 22.2

32) If two of the hydrogen atoms in ethylene, H2C═CH2, are replaced by two chlorine atoms to form dichloroethylene, how many different dichloroethylene isomers can there be?

A) 1

B) 2

C) 3

D) 4

E) 6

Diff: 2

Section: 22.2

33) If two of the hydrogen atoms in ethylene, H2C═CH2, are replaced by one chlorine atom and one fluorine atom to form chlorofluoroethene, C2H2ClF, how many different chlorofluoro-ethene isomers can there be?

A) 1

B) 2

C) 3

D) 4

E) 6

Diff: 2

Section: 22.2

34) Various hydrocarbons can be separated from a crude oil mixture by

A) filtration.

B) chromatography.

C) precipitation.

D) fractional distillation.

E) centrifugation.

Diff: 2

Section: 22.2

35) When CH3—CH═CH2 is reacted with water in the presence of a catalytic amount of acid, a new compound is formed. What might be the product of this reaction?

A) CH3—CH—CH2

B)

The structure of the compound has a three-carbon chain, in which C 1 is bonded to a hydroxyl group. C 2 is bonded to the oxygen atom of a water molecule.

C)

The structure of the compound has a three-carbon chain, in which C 2 is bonded to a hydroxyl group.

D)

The structure of the compound has a three-carbon chain, in which C 2 is double-bonded to an oxygen.

E)

The structure of the compound has a three-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to a hydrogen atom.

Diff: 2

Section: 22.2

36) The general structural formula for an ether is

A)

The general structure of a compound has a central carbon atom, which is double-bonded to an oxygen atom, single-bonded to a hydrogen atom and an R group.

B)

The general structure of a compound has a two-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to a hydrogen atom. C 2 is bonded to an R group.

C)

The general structure of a compound has a two-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an R prime group. C 2 is bonded to an R group.

D)

The general structure of a compound has a central carbon atom, which is double-bonded to an oxygen atom, single-bonded to an R group and an R prime group.

E) R—O—R'

Diff: 2

Section: 22.1

37) Which formula is an alcohol?

A)

The general structure of a compound has a central carbon atom, which is double-bonded to an oxygen atom, single-bonded to an R group and a hydrogen atom.

B)

The general structure of a compound has a central carbon atom, which is double-bonded to an oxygen atom, single-bonded to an R group and a hydroxyl group.

C)

The general structure of a compound has a central carbon atom, which is double-bonded to an oxygen atom, single-bonded to an R group and an oxygen atom. The single-bonded oxygen atom is single-bonded to an R group.

D)

The general structure of a compound has a central carbon atom, which is double-bonded to an oxygen atom, single-bonded to an R group and an R prime group.

E)

The general structure of a compound has a central carbon atom, which is single-bonded to an oxygen atom, a hydrogen atom, an R group and an R prime group.

Diff: 1

Section: 22.3

38) Which is a product of the oxidation of CH3—CH2—CH2—O—H?

A)

The structure of a compound has a three-carbon chain, in which C 2 is double-bonded to an oxygen atom.

B)

The structure of a compound has a three-carbon chain. C 1 is double-bonded to an oxygen atom and single-bonded to a hydroxyl group.

C) CH3—CH2—CH3

D)

The structure of a compound has a two-carbon chain. C 1 is double-bonded to an oxygen atom and single-bonded to another oxygen atom. The single-bonded oxygen atom is further bonded to a methyl group.

E) CH3—CH2—O—CH3

Diff: 2

Section: 22.3

39) The functional group C═O is found in

A) alkenes.

B) ketones.

C) amines.

D) alcohols.

E) ethers.

Diff: 1

Section: 22.3

40) The functional group C═O is found in all the species below except

A) aldehydes.

B) ketones.

C) amides.

D) ethers.

E) esters.

Diff: 1

Section: 22.3

41) The functional group C═O is found in all the species below except

A) aldehydes.

B) carboxylic acids.

C) amides.

D) amines.

E) esters.

Diff: 1

Section: 22.3

42) The compound below is classified as which type of compound?

The structure of a compound has a three-carbon chain, in which C 2 is double-bonded to an oxygen atom.

A) aldehyde

B) ketone

C) acid

D) ester

E) amine

Diff: 1

Section: 22.3

43) The compound below is classified as which type of compound?

The structure of a compound has a fourteen-carbon chain, in which C 5 is replaced by an oxygen atom carrying two-lone pairs of electrons.

A) amine

B) amide

C) aromatic

D) ester

E) ether

Diff: 1

Section: 22.3

44) The compound below is classified as which type of compound?

The structure of a compound has a three-carbon chain, in which C 1 is bonded to an N H 2 group.

A) amine

B) amide

C) aromatic

D) ester

E) ether

Diff: 1

Section: 22.3

45) The compound below is classified as which type of compound?

The structure of a compound has a three-carbon chain, in which C 1 is single-bonded to a nitrogen atom and double-bonded to an oxygen atom. The nitrogen atom is further bonded to an ethyl group and a methyl group.

A) amine

B) amide

C) aromatic

D) ester

E) ether

Diff: 1

Section: 22.3

46) The compound below is classified as which type of compound?

The structure of a compound has a three-carbon chain, in which C 1 is single-bonded to an oxygen atom and double-bonded to an oxygen atom. The single-bonded oxygen atom is further bonded to an ethyl group.

A) amine

B) amide

C) aromatic

D) ester

E) ether

Diff: 1

Section: 22.3

47) The compound below has which functional groups?

The structure of a compound has a five-membered carbon ring, in which C 1 is replaced by an oxygen atom. C 2 is bonded to a C H group and double-bonded to an oxygen atom. C 5 is double-bonded to an oxygen atom. Each oxygen atom in the structure carries two lone pairs of electrons.

A) ketone and ester

B) ketone, alcohol, and carboxylic acid

C) ether, ketone, and aldehyde

D) ether and aldehyde

E) ketone and aldehyde

Diff: 1

Section: 22.3

48) The compound below is classified as which type of compound?

The structure of a compound has a four-carbon chain, in which C 2 is double-bonded to an oxygen atom.

A) aldehyde

B) ketone

C) acid

D) ester

E) amine

Diff: 1

Section: 22.3

49) The compound below is classified as which type of compound?

The structure of a compound has a four-carbon chain. C 1 is double-bonded to an oxygen atom and single-bonded to a hydroxyl group.

A) ketone

B) aldehyde

C) ester

D) carboxylic acid

E) amide

Diff: 1

Section: 22.3

50) The compound below is named

The structure of a compound has a four-carbon chain, in which C 2 is double-bonded to an oxygen atom.

A) butanamine.

B) butanamide.

C) butanketone.

D) 2-butanone.

E) 2-butanal.

Diff: 1

Section: 22.3

51) The compound below has which functional groups?

The structure of a compound has a six-membered carbon ring, in which C 1 is single-bonded to a hydroxyl group. C 2 is single-bonded to an oxygen atom. C 4 is double-bonded to C 5. C 3 is bonded to a C H group, which is further bonded to two C H 2 group forming a bicyclo ring. The first C H 2 group is further bonded to the oxygen atom, which is bonded to C 2 of the six-carbon ring. The second C H 2 group is bonded to another C H 2 group, which is further bonded to C 6 of the six-carbon ring. Each carbon atom in the structure carries two lone pairs of electrons.

A) aromatic, alcohol, and ether

B) aromatic, alcohol, and ester

C) ether, alkene, and alcohol

D) ester, alkene and alcohol

E) ether and ester

Diff: 2

Section: 22.3

52) The compound below has which functional groups?

The structure of a compound has a two-carbon chain, in which C 1 is single bonded to an oxygen atom and double-bonded to an oxygen atom. The single-bonded oxygen atom is further bonded to an ethyl group. C 2 is bonded to a hydroxyl group.

A) alcohol and ester

B) amide, ether, and aldehyde

C) ether and amine

D) ester and amine

E) amine, alcohol, and ether

Diff: 2

Section: 22.3

53) The compound below is named

The structure of a compound has a five-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to a hydrogen atom.

A) pentaketone.

B) pentaldehyde.

C) pentanal.

D) pentanone.

E) pentanoic acid.

Diff: 2

Section: 22.3

54) The ester that is prepared by heating 1-pentanol with acetic acid in the presence of an acidic catalyst is named

A) acetic pentanoate.

B) pentanoic acetate.

C) 1-pentyl acetate.

D) acetyl 1-pentanoate.

E) acetyl pentanol.

Diff: 2

Section: 22.3

55) Ethyl propanoate is a(n)

A) carboxyl alcohol.

B) aldehyde.

C) alcohol.

D) ester.

E) amide.

Diff: 1

Section: 22.3

56) The compound below has which functional groups?

The structure of a compound has a benzene ring fused with a six-membered carbon ring, in which C 1 is replaced by an N H group. C 4 is double-bonded to an oxygen atom carrying two lone pairs of electrons. C 5 is double-bonded to C 6.

A) ester, amide, carboxylic acid

B) aromatic, ketone, amine

C) aromatic, ketone, amide

D) aromatic, aldehyde, amide

E) aromatic, aldehyde, amine

Diff: 2

Section: 22.4

57) Which is a product of the oxidation of the following:

The structure of a compound has a three-carbon chain, in which C 2 is single-bonded to a hydroxyl group.

A)

The structure of a compound has a three-carbon chain, in which C 2 is double-bonded to an oxygen atom.

B)

The structure of a compound has a two-carbon chain, in which C 1 is single bonded to an oxygen atom and double-bonded to an oxygen atom. The single-bonded oxygen atom is further bonded to a methyl group.

C) CH3—CH2—CH3

D)

The structure of a compound has a two-carbon chain, in which C 1 is single-bonded to a hydroxyl group and double-bonded to an oxygen atom.

E) CH3—CH2—O—CH3

Diff: 2

Section: 22.3

58) The reaction of (CH3)2CH⎯CH2⎯O⎯H with concentrated HBr using controlled heating yields

A) CH3—CH2—CH2—Br

B) (CH3)2CH—CH2—Br

C) (CH3)2CH—CH2—O—Br

D) (CH3)2CH—CH4+ Br−

E) (CH3)2CH—CH3

Diff: 2

Section: 22.3

59) Based on the properties of the attached functional group, which compound would you expect to interact most strongly with water, thus making it the substance most soluble in water?

Hint: Consider hydrogen bonds.

A) CH3—CH2—Cl

B) CH3—CH2—F

C) CH3—CH2—I

D) CH3—CH2—S—H

E) CH3—CH2—O—H

Diff: 3

Section: 22.3

60) Cyclohexyl propanoate is a(n)

A) aldehyde.

B) ketone.

C) carboxylic acid.

D) ester.

E) amide.

Diff: 2

Section: 22.3

61) Based on the properties of the attached functional group, which compound below would you expect to interact most strongly with water, thus making it the most soluble compound?

Hint: Consider hydrogen bonds.

A) CH3—CH2—H

B) CH3—CH2—NH2

C) CH3—O—CH3

D) CH3—CH2—I

E) CH3—CH2—S—H

Diff: 3

Section: 22.4

62) Which compound is least soluble in water?

A)

The structure of a compound has a five-membered carbon ring, in which C 1 is replaced by an N H group.

B)

The structure of a compound has a five-membered carbon ring.

C)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an oxygen atom.

D)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an N H group.

E)

The structure of a compound has a six-membered carbon ring, in which C 1 and C 4 each is replaced by an oxygen atom.

Diff: 1

Section: 22.4

63) Which compound is least soluble in water?

A)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an N H group.

B)

The structure of a compound has a six-membered carbon ring.

C)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an oxygen atom.

D)

The structure of a compound has a five-membered carbon ring, in which C 1 is replaced by an oxygen atom.

E)

The structure of a compound has a six-membered carbon ring, in which C 1 and C 4 each is replaced by an oxygen atom.

Diff: 1

Section: 22.4

64) Which compound is a Brønsted base?

A)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an N H group.

B)

The structure of a compound has a five-membered carbon ring.

C)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an oxygen atom.

D)

E)

The structure of a compound has a six-membered carbon ring, in which C 1 and C 4 each is replaced by an oxygen atom.

Diff: 1

Section: 22.4

65) Which one of the species below is soluble in dilute HCl(aq)?

A)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an N H group. C 3 is single-bonded to eight repeating units of a C H 2 group, which is further bonded to a methyl group.

B)

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an oxygen atom.

C)

The structure of a compound has a six-membered carbon ring, in which C 1 is bonded to a chlorine atom.

D)

The structure of a compound has a six-membered carbon ring, in which C 1 is bonded to a bromine atom.

E)

The structure of a compound has a five-membered carbon ring, in which C 1 is replaced by an oxygen atom.

Diff: 1

Section: 22.4

66) Which compound is insoluble in water?

A) CH3CH─O─H

B) CH3(CH2)8─CH─O─H

C) CH3(CH2)8─CH─NH2

D) CH3CH2─Cl

E) CH3CH2─H

Diff: 1

Section: 22.4

67) A functional group containing nitrogen is found in

A) alkenes.

B) alcohols.

C) amines.

D) carboxylic acids.

E) ethers.

Diff: 1

Section: 22.4

68) One of the compounds listed is an organic base that functions as a proton acceptor. Identify this

organic base.

A) CH3—CH2—CH2—O—H

B) CH3—CH═CH2

C)

The structure of a compound has a three-carbon chain, in which C 2 is double-bonded to an oxygen atom.

D)

The structure of a compound has a three-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to a hydrogen atom.

E) CH3—CH2—NH2

Diff: 1

Section: 22.4

69) The compound, trimethylamine is a(n) ________ and has the formula ________.

A) base, (CH3NH2)3

B) base, (CH3)3NH2

C) acid, (CH3)3NH2

D) base, (CH3)3N

E) acid, (CH3)3(NH2)2

Diff: 1

Section: 22.4

70) Dodecylamine, CH3(CH2)10CH2NH2, is insoluble in water. Yet, it can be converted to a water soluble form. Which of the species below represents a water soluble form of this compound?

A) CH3(CH2)10CH2NH2—O—H

B) CH3(CH2)10CH2NH2—Cl

C) CH3(CH2)10CH2NH—CH3

D) CH3(CH2)10CH2NH3+ Cl−

E) CH3(CH2)10CH2NH2—O—CH3

Diff: 2

Section: 22.4

71) Octylamine, CH3(CH2)7NH2, is insoluble in water. Yet, it can be converted to a water soluble form. Which of the species below represents a water-soluble form of this compound?

A) CH3(CH2)7NH2—O—H

B) CH3(CH2)7NH2—Cl

C) CH3(CH2)7NH—CH3

D) CH3(CH2)7NH3+ Cl−

E) CH3(CH2)7NH2—O—CH3

Diff: 2

Section: 22.4

72) The compound below has which functional groups?

The structure of a compound has a benzene ring. C 1 is bonded to a carbon atom, which is double-bonded to an oxygen atom carrying two lone pairs of electrons and single-bonded to an N H 2 group. The nitrogen atom carries a lone pair of electrons.

A) aromatic and carboxylic acid

B) aromatic and amide

C) aromatic and amine

D) aromatic and alcohol

E) aromatic and aldehyde

Diff: 2

Section: 22.4

73) The compound below has which functional groups?

The structure of a compound has a five membered carbon ring, in which C 1 is replaced by an N H group. C 2 is double-bonded to C 3 and C 4 is double-bonded to C 5. C 2 is also single-bonded to a carbon atom, which is single-bonded to an N H group and double-bonded to an oxygen atom carrying two lone pairs of electrons. The N H group is further bonded to C 1 of a three-carbon chain. C 3 of the three-carbon chain is bonded to C 2 of a five membered carbon ring, in which C 1 is replaced by an N H group. C 2 is double-bonded to C 3 and C 4 is double-bonded to C 5.

A) ester and amide

B) amide and amine

C) aldehyde and amine

D) carboxylic acid and amine

E) ester and amine

Diff: 1

Section: 22.4

74) The compound below is which type of compound?

The structure of a compound has a two-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an N H 2 group.

A) aldehyde

B) amine

C) ester

D) amide

E) amino acid

Diff: 1

Section: 22.4

75) The compound below is named

The structure of a compound has a five-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an N H 2 group.

A) pentanamine.

B) pentamine.

C) 1-pentanamide.

D) pentanamide.

E) pentaketoneamine.

Diff: 1

Section: 22.4

76) For the following segment of a polymer, what would be the expected monomer used to make it?

The structure of a compound has a nine-carbon chain, in which C 1, C 3, C 5, and C 7 is double-bonded to C 2, C 4, C 6, and C 8, respectively. C 2, C 4, C 6, and C 8 each is bonded to an A group. C 3, C 5, and C 7 each is bonded to an X group.

A)

The structure of a compound has a two-carbon chain, in which C 1 is triple-bonded to C 2. C 1 and C 2 is bonded to an X group and an A group, respectively.

B) HC=CH

C)

The structure of a compound has a four-carbon chain, in which C 1 and C 3 is double-bonded to C 2 and C 4, respectively. C 1 and C 3 is bonded to an X group. C 2 and C 4 each is bonded to an A group.

D)

The structure of a compound has a two-carbon chain, in which C 1 is bonded to an X group and C 2 is bonded to an A group.

E)

The structure of a compound has a two-carbon chain, in which C 1 is double-bonded to C 2. C 1 and C 2 is bonded to an X group and an A group, respectively.

Diff: 2

Section: 22.6

77) Polymers formed by the addition of monomer units by an initiator are often called

A) unit polymers.

B) chain-growth polymers.

C) branching polymers.

D) condensation polymers.

E) background polymers.

Diff: 2

Section: 22.6

78) A polymer is formed by the removal of water from the monomer mixture are often called

A) unit polymers.

B) chain-growth polymers.

C) branching polymers.

D) condensation polymers.

E) background polymers.

Diff: 2

Section: 22.6

79) Which of the following is a true statement with respect to molecular mass and strength?

A) High molecular mass polymers tend to be gases.

B) High molecular mass polymers tend to have low strength.

C) Low molecular mass polymers tend to have low strength.

D) All polymers have high strength and molecular mass.

E) Molecular mass tends to have no effect on polymer strength.

Diff: 2

Section: 22.6

80) Which functional group is not usually found in carbohydrates?

A) aldehyde

B) amide

C) ether

D) hydroxy

E) ketone

Diff: 2

Section: 22.6

81) A compound which dissolves in hydrochloric acid is

A)

The structure of a compound has a central carbon atom double-bonded to an oxygen atom and single-bonded to two N H 2 groups.

B) H3C—CH2—O—H

C)

The structure of a compound has a three-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an N H 2 group.

D)

The structure of a compound has a four-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to a hydroxyl group.

E) H3C—CH2—CH2—NH2

Diff: 2

Section: 22.4

82) Which species is not a carbohydrate?

A) lactose

B) glucose

C) glycogen

D) glycerol

E) amylose

Diff: 1

Section: 22.6

83) Which fall into the class of compounds called carbohydrates?

A) naturally occurring polyesters

B) naturally occurring polyamides

C) naturally occurring polyalkenes

D) naturally occurring polyaldehydes

E) naturally occurring polycarboxylic acids

Diff: 1

Section: 22.6

84) Which fall into the class of compounds called carbohydrates?

A) naturally occurring polyesters

B) naturally occurring polyamides

C) naturally occurring polyketones

D) naturally occurring polyalkenes

E) naturally occurring polycarboxylic acids

Diff: 1

Section: 22.6

85) Lipids, by definition, are naturally occurring compounds that

A) contain ester groups.

B) contain cholesterol.

C) contain fatty acids as structural units.

D) are water insoluble but soluble in nonpolar solvents.

E) are unsaturated.

Diff: 1

Section: 22.6

86) Triacylglycerols are compounds that contain combined

A) fatty acids and choline.

B) fatty acids and glycerol.

C) fatty acids and phospholipids.

D) cholesterol and other steroids.

E) lecithin and choline.

Diff: 1

Section: 22.6

87) The chemical bond that links glycerol to a fatty acid is an example of what type of linkage?

A) ether

B) peptide

C) ester

D) ionic

E) hydrogen bond

Diff: 1

Section: 22.6

88) Proteins are polymers. They consist of monomer units called

A) aldehydes.

B) ketones.

C) amines.

D) amides.

E) amino acids.

Diff: 1

Section: 22.6

89) A particular polypeptide can be represented as Gly-Ala-Phe-Cys-Gly-Ala-Phe-Cys. How many peptide bonds are there in this polypeptide?

A) 2

B) 4

C) 7

D) 8

E) 9

Diff: 1

Section: 22.6

90) A particular polypeptide can be represented as Gly-Ala-Phe-Cys-Gly-Ala-Phe-Cys. How many sites with positive or negative charges are in this polypeptide?

A) 2

B) 4

C) 7

D) 8

E) 9

Diff: 1

Section: 22.6

91) Which one of the following compounds is an amino acid?

A)

The structure of a compound has a central carbon atom double-bonded to an oxygen atom. The central carbon atom is also single-bonded to an N H 3 group carrying a positive charge and an oxygen atom carrying a negative charge.

B)

The structure of a compound has a central carbon atom double-bonded to an oxygen atom. The central carbon atom is also single-bonded to an N H 4 group carrying a positive charge and an oxygen atom carrying a negative charge.

C)

The structure of a compound has a central carbon atom double-bonded to an oxygen atom. The central carbon atom is also single-bonded to an N H 3 group carrying a positive charge and an N H 2 group.

D)

The structure of a compound has a two-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an oxygen atom carrying a negative charge. C 2 is single-bonded to an N H 3 group carrying a positive charge.

E)

The structure of a compound has a two-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an N H 3 group carrying a positive charge. C 2 is single-bonded to an oxygen atom carrying a negative charge.

Diff: 1

Section: 22.6

92) Carbohydrates are polymers. They consist of monomer units called

A) fatty acids.

B) amino acids.

C) nucleotides

D) monosaccharides.

E) steroids.

Diff: 1

Section: 22.6

93) When lard (pig fat) is hydrolyzed, the products are

A) amino acids.

B) alcohols and lipids.

C) glycerol and lipids.

D) carbohydrates.

E) glycerol and fatty acids.

Diff: 2

Section: 22.6

94) Which compound is not a lipid?

A) andosterone

B) glucose

C) cholesterol

D) testosterone

E) triacylerol

Diff: 2

Section: 22.6

95) Which of the following are polypeptides?

A) carbohydrates

B) fats

C) amino acids

D) proteins

E) steroids

Diff: 2

Section: 22.6

96) DNA is a(n)

A) enzyme.

B) nucleic acid.

C) protein.

D) peptide.

E) steroid.

Diff: 2

Section: 22.7

97) Disaccharides are best characterized as

A) two monosaccharides linked by an oxygen bond.

B) two amino acids linked by a peptide bond.

C) two monosaccharides linked by a nitrogen bond.

D) two peptides linked by a hydrogen bond.

E) two glycogens linked by a fatty acid.

Diff: 1

Section: 22.6

98) What is the major biological function of the glycogen biomolecule?

A) It stores amino acids for later use.

B) It stores glucose for later use.

C) It is a major building block of proteins.

D) It is used to make disaccharides.

E) It stores sucrose for later use.

Diff: 2

Section: 22.6

99) Which base does thymine bond to in DNA?

A) adenine

B) uracil

C) guanine

D) cytosine

E) glucose

Diff: 1

Section: 22.7

100) Which base does guanine bond to in DNA?

A) thymine

B) uracil

C) adenine

D) cytosine

E) glucose

Diff: 1

Section: 22.7

101) The process in which DNA produces a complementary sequence of bases on RNA is called

A) duplication.

B) replication.

C) translation.

D) transcription.

E) helixing.

Diff: 1

Section: 22.7

102) The process in which RNA converts their base sequence into a new polypeptide is called

A) duplication.

B) replication.

C) translation.

D) transcription.

E) helixing.

Diff: 1

Section: 22.7

103) The huge number of organic compounds, greater than all other kinds put together, is made possible by the ability of ________ to ________.

Diff: 1

Section: 22.1

104) The hydrocarbon group formed by removal of one hydrogen from methane is called ________.

Diff: 1

Section: 22.1

105) Draw all the isomers of C5H12 using lines segment (stick) notation.

An illustration depicts the three possible isomers of C 5 H 12. The bond-line structure of the first isomer has a five-carbon zigzag chain. The bond-line structure of the second isomer has a four-carbon zigzag chain, in which C 2 is bonded to a methyl group. The bond-line structure of the third isomer has a three-carbon chain, in which C 2 is bonded to 2 methyl groups.

Diff: 1

Section: 22.1

106) Draw all the isomers of C6H14 using lines segment (stick) notation.

An illustration depicts the three possible isomers of C 6 H 14. The bond-line structure of the first isomer has a six-carbon zigzag chain. The bond-line structure of the second isomer has a five-carbon zigzag chain, in which C 2 is bonded to a methyl group. The bond-line structure of the third isomer has a four-carbon zigzag chain, in which C 2 and C 3 each is bonded to a methyl group. The bond-line structure of the fourth isomer has a five-carbon zigzag chain, in which C 2 is bonded to a methyl group. The bond-line structure of the fifth isomer has a four-carbon chain, in which C 2 is bonded to 2 methyl groups.

Diff: 1

Section: 22.1

107) State how many isomers of C2H2Cl2 and draw them.

Hint: This molecule has a double bond.

An illustration depicts the three possible isomers of C 2 H 2 C l 2. The bond-line structure of the first isomer has a two-carbon chain, in which C 1 is double-bonded to C 2. C 1 is single-bonded to a chlorine atom at the top left and a hydrogen atom at the bottom left. C 2 is single-bonded to a chlorine atom at the bottom right and a hydrogen atom at the top right. The bond-line structure of the second isomer has a two-carbon chain, in which C 1 is double-bonded to C 2. C 1 is single-bonded to a chlorine at the top left and a hydrogen atom at the bottom left. C 2 is single-bonded to a chlorine at the top right and a hydrogen atom at the bottom right. The bond-line structure of the third isomer has a two-carbon chain, in which C 1 is double-bonded to C 2. C 1 is single-bonded to a chlorine atom at the top left and another chlorine atom at the bottom left. C 2 is single-bonded to a hydrogen at the top right and another hydrogen atom at the bottom right.

Diff: 2

Section: 22.2

108) The IUPAC name, or names, for the organic structure CH3—CH═CH—CH3, is/are ________.

Diff: 1

Section: 22.2

109) What is the correct structure for 2,3,3-trimethylpentane?

The correct structure of 2, 3, 3-trimethylpentane has a five-carbon chain, in which C 2 is bonded to a methyl group and C 3 is bonded to 2 methyl groups.

Diff: 2

Section: 22.2

110) What is the correct structure for trans-2,3-dibromo-2-pentene?

The correct structure of trans-2, 3-dibromo-2-pentene has a five-carbon chain, in which C 2 is double-bonded C 3 and single-bonded to a bromine atom at the bottom right. C 3 is single-bonded to a bromine atom at the top left.

Diff: 2

Section: 22.2

111) What is the correct structure for 4,4-dibromo-2-pentyne?

The correct structure of 4, 4-dibromo-2-pentyne has a five-carbon chain, in which C 2 is triple-bonded to C 3. C 4 is single-bonded to 2 bromine atoms.

Diff: 2

Section: 22.2

112) What is the correct structure for 3-bromo-3-methyl-1-pentene?

The correct structure of 3-bromo-3-methyl-1-pentene has a five-carbon chain, in which C 1 is double-bonded C 2. C 3 is single-bonded to a bromine atom and a methyl group.

Diff: 2

Section: 22.2

113) Draw the product of the following reaction:

An illustration depicts an incomplete chemical equation. The reactants toluene and H N O 3 reacts in the presence of H 2 S O 4 as catalyst to yield the product, which is not given. The structure of the toluene has a benzene ring, in which C 1 is bonded to a methyl group.

The structure of the product has a benzene ring, in which C 1 is bonded to a methyl group and C 2 is bonded to a nitro group.

Diff: 2

Section: 22.2

114) Draw the product of the following reaction:

An illustration depicts an incomplete chemical equation. The reactants undecene and H B r reacts to yield the product, which is not given. The structure of the undecene has an eleven-carbon zigzag chain, in which C 5 is double-bonded to C 6.

Hint: Consider where the carbocation is most likely to form.

The structure of the product has an eleven-carbon zigzag chain, in which C 5 is bonded to a hydrogen atom and C 6 is bonded to a bromine atom.

Diff: 3

Section: 22.2

115) Draw the product of the following reaction:

Hint: Water is an elimination product.

The structure of the product has a five-carbon zigzag chain, in which C 1 is double-bonded to C 2.

Diff: 3

Section: 22.3

116) ________ are the major industrial source of hydrocarbon compounds.

Diff: 1

Section: 22.2

117) The name of the alkane hydrocarbon whose carbon backbone is shown below is ________.

The structure of the compound has a seven-carbon chain, in which C 2 is bonded to a methyl group. C 3 and C 5 each is bonded to 2 methyl groups.

Diff: 1

Section: 22.2

118) The compound shown below is an example of which functional group?

The structure of a compound has a six-membered carbon ring, in which C 1 is replaced by an oxygen atom.

Diff: 1

Section: 22.3

119) An important property of carboxylic acids is that they are organic ________.

Diff: 1

Section: 22.3

120) The ________ functional group is the functional group that gives organic acids.

Diff: 1

Section: 22.3

121) When the ester, isopropyl butanoate is hydrolyzed in the presence of catalytic amounts of a strong base, two compounds are obtained. Their names are ________ and ________.

Hint: This reaction is also called saponification.

Diff: 3

Section: 22.3

122) The compound, H3C—CH2—O—H, is a member of what family of organic compounds?

Diff: 1

Section: 22.3

123) The compound, H3C—CH2—CH2—NH2, is a member of what family of organic compounds?

Diff: 1

Section: 22.4

124) The compound, H3C—CH2—O—CH3, is a member of what family of organic compounds?

Diff: 1

Section: 22.3

125) An important property of amines is that they are organic ________.

Diff: 1

Section: 22.4

126) The ________ functional group is the functional group that gives organic bases.

Diff: 1

Section: 22.3

127) Identify all the functional groups found in the compound below.

The structure of a compound has a benzene ring, in which C 1 is bonded to a carboxylic group and C 4 is bonded to an N H 2 group.

Diff: 1

Section: 22.3

128) Identify all the functional groups found in the compound below.

The structure of a compound has a four-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an N H 2 group. C 4 is bonded to an oxygen atom, which is further bonded to a methyl group.

Diff: 1

Section: 22.3

129) Identify all the functional groups found in the compound below.

The structure of a compound has a three-carbon chain, in which C 1 is double-bonded to an oxygen atom and single-bonded to an oxygen atom, which is further bonded to a methyl group. C 3 is bonded to a hydroxyl group.

Diff: 1

Section: 22.3

130) The amide formed when formic acid is heated with ammonia is ________ (name and formula).

The structure of formamide has a central carbon atom double-bonded to an oxygen atom; single-bonded to a hydrogen atom and an N H 2 group.

Diff: 2

Section: 22.4

131) Proteins are polymers. They consist of monomer units called ________.

Diff: 1

Section: 22.6

132) DNA is found to exist as a ________ structure in our body.

Diff: 2

Section: 22.6

133) Complete the following sequence. DNA undergoes transcription to produce RNA. RNA undergoes translation to produce ________, which are the building blocks of proteins.

Diff: 1

Section: 22.6

134) A reactive group, called a functional group, which is attached to the hydrocarbon portion of a molecule, influences or determines the kinds of reactions the molecule undergoes.

Diff: 1

Section: 22.1

135) Hydrocarbons can be gases, liquids or solids.

Diff: 1

Section: 22.1

136) Polymers with high molecular mass tend to have high strength.

Diff: 1

Section: 22.5

137) How many different carbon chains can be drawn for the C5H12 hydrocarbon? This is the same as the number of isomers of C5H12 that can exist.

A) 1 (no isomers)

B) 2

C) 3

D) 4

E) 5

Diff: 1

Section: 22.1

138) What is the systematic name for the following structure?

The structure of the compound has an eight-carbon chain, in which C 3 is double-bonded to C 4. C 2 and C 6 each is bonded to a methyl group. C 5 is bonded to an ethyl group. C 7 is bonded to a bromine atom.

A) 2-bromo-4-ethyl-3,7-dimethyloctane

B) 2-bromo-4-ethyl-3,7-dimethyl-5-octene

C) bromoethyldimethyloctene

D) 7-bromo-5-ethyl-2,6-dimethyl-3-octene

E) 6-bromo-4-ethyl-1,1,5-trimethyl-2-heptane

Diff: 2

Section: 22.2

139) A carbonyl compound with 6 carbons was hydrogenated in a high pressure apparatus at 300°C using a hydrogenation catalyst. The product had the formula,

The structure of the compound has a five-carbon chain, in which C 3 is bonded to a hydroxyl group.

The original carbonyl compound was therefore ________.

Diff: 2

Section: 22.3

140) An ester with 6 carbons was hydrolyzed in the presence of catalytic amounts of a base to yield two compounds, one of which was a 4 carbon acid with a branched chain. What is the name of the other product of the reaction?

Hint: This reaction is also called saponification.

Diff: 3

Section: 22.3

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DOCX
Chapter Number:
22
Created Date:
Aug 21, 2025
Chapter Name:
Chapter 22 Organic Compounds, Polymers, And Biochemicals
Author:
Neil D. Jespersen

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